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Volume 7, Issue 2 (Suppl)

J Adv Chem Eng, an open access journal

ISSN: 2090-4568

Euro Chemical Engineering 2017

November 16-17, 2017

ADVANCES IN CHEMICAL ENGINEERING AND TECHNOLOGY

November 16-17, 2017 | Paris, France

2

nd

International Conference on

Amino acids as gas hydrate inhibitors for offshore oil and gas industry

M Fahed Qureshi

1

, Tausif AlTamash

1

, Majeda Khraisheh

1

, Mohammad Ali Saleh

1

and

Mert Atilhan

2

1

Qatar University, Qatar

2

Texas A&M University, USA

N

atural gas hydrates are crystalline compounds that are formed under higher pressure and low temperature conditions when

small gas molecules like methane and ethane get trapped within the water molecules and form clusters. The formation

of these hydrate clusters is a major threat to offshore flow assurance, as they can lead to unwanted blockages in the subsea

pipelines and cause safety concerns. So, in order to avoid the risk of hydrate formation, the offshore oil and gas industry heavily

relies on the use of thermodynamic hydrate inhibitors (THI) like methanol and mono-ethylene glycol (MEG). These THI does

help to mitigate hydrate formation, but they are required in bulk quantity (>30 wt%), are highly flammable and cannot be

easily dispose of into the environment. So in order to avoid environmental concerns related to the use of THI, the researchers

are looking for hydrate inhibitors that are environmentally friendly, cheap and are required in low dosage. Amino acids are

bio molecules containing amine (-NH2) and carboxyl (-COOH) functional groups, that are known to be biodegradable,

environmentally friendly, readily available and cheaper than ionic liquids. They are considered to be building blocks of life and

are widely used in the manufacturing of pharmaceutical drugs and food

products.In

this work, the effectiveness of amino acids

as the gas hydrate inhibiter has been tested using pure methane gas and the rocking cell assembly (RC-5). The selected amino

acids (AA) included: L-Alanine, Glycine, L-Histidine, L-Phenylalanine and L-Asparagine. The experiments were carried out at

different AA concentrations (1-5wt %) and within the pressure range of 40-120 bars. The experimental results indicate that the

selected AA perform better as a kinetic hydrate inhibitor (KHI) and the addition of synergent compounds like poly-ethylene

oxide (PEO) with AA help to improve their kinetic inhibition effectiveness significantly

Acknowledgment:

Author M Fahed Qureshi would like to acknowledge GSRA. This work was made possible by GSRA # 2-1-0603-14012 from

the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are solely the responsibility

of the authors.

Figure 1

:

Basic Amino acid structure

Biography

M Fahed

Qureshi.is

currently a PhD fellow at Qatar University conducting research on improving effectiveness of low environmental impact gas hydrate inhibitors.

He holds MSc degree in Chemical Process Research & Development from University of Leeds UK and has previously worked with Total E& P Qatar in Acid

Stimulation project. Currently, he has three publications in the field of gas hydrates and has been awarded Graduate studies research award for his PhD work by

Qatar National Research Funds (QNRF). He enjoys writing and is interested in entrepreneurship.

Mqureshi@qu.edu.qa

M Fahed Qureshi et al., J Adv Chem Eng 2017, 7:2(Suppl)

DOI: 10.4172/2090-4568-C1-002