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Journal of Analytical & Bioanalytical Techniques | ISSN: 2155-9872 | Volume 9
World HPLC, Separation Techniques & Pharmacovigilance
World Analytical Chemistry & Mass Spectrometry
18
th
International Conference on
August 29-30, 2018 | Toronto, Canada
&
Structural investigation of Fe(III) and Ga(III) complexes with aromatic hydrazones by ESI MS/MS
Nives Galic
1
, Darko Kontrec
2
and
Sasa Kazazic
2
1
University of Zagreb, Croatia
2
Ruder Boskovic Institute, Croatia
A
roylhydrazones can act as neutral, monoanionic or dianionic ONO tridentate ligands [1]. The coordination abilities of
aromatic hydrazones derived from nicotinic acid hydrazide and differently substituted 2-hydroxybenzaldehydes towards
Fe
3+
and Ga
3+
will be discussed. Different techniques, like UV-Vis, vibrational spectroscopy and mass spectrometry were used
for structural investigation of the complexes in solution and in the solid state. In this work, the ESI MS and MS/MS spectra,
including fragmentation pathways of Fe(III) and Ga(III) complexes with aroylhydrazones are presented.
Biography
Nives Galic was born in Zagreb, Croatia. She received a Ph.D. degree in Analytical Chemistry (1999). In 2016 she was elected to the position of Full Professor.
During the period 2011-2017 she was the Head of the Division of Analytical Chemistry. She is a leader of the project funded by Croatian Science Foundation (IP-
2014-09-4841).
ngalic@chem.pmf.hrNives Galic et al., J Anal Bioanal Tech 2018, Volume 9
DOI: 10.4172/2155-9872-C1-028