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conferenceseries

.com

September 02-03, 2019 | Berlin, Germany

6

th

World Conference on Climate Change

Volume 10

Journal of Earth Science & Climatic Change

ISSN: 2157-7617

Climate Change 2019

September 02-03, 2019

Mineralization of CO

2

for Carbon Sequestration using Flue Gas Desulphurization Gypsum

Jonathan Riddle

and

Rona J. Donahoe

The University of Alabama, USA

P

ast efforts for carbon sequestration using CO

2

mineralization have proven effective for long-term stable storage of

CO

2

but were prohibitive due to slow reaction rates and high cost. Recent mineralization studies reacting flue gas

desulphurization (FGD) gypsum (CaSO

4

•2H

2

O) with CO

2

in an alkaline solution, have shown conversion of gypsum

into calcium carbonate (CaCO

3

) to be a rapid and effective method for carbon sequestration. However, these studies

used sodium hydroxide and ammonia to increase solution pH. The use of ammonia makes this mineralization

method inefficient due to the production of ammonia being a significant CO

2

source. The goal of this study was to

obtain high FGD gypsum-to-calcite conversation percentages at ambient temperature while eliminating the need for

ammonia. A stirred reactor was utilized to study the effects of P

CO2

(10, 30, 60, and 250 psi), solution pH (12, 13, 13.5

and 14), solid-to-solution ratio (1:100, 1:80, 1:40, 1:100), and reaction time (10, 15, 30, and 120+ minutes) variation

on the rate of conversion. The amount of carbonate produced was calculated from Rietveld refinement of XRD

patterns to determine the impact of each variable. Experimental results showed varying degrees of FGD gypsum

to CaCO

3

conversion. Solution pH was a primary control on conversion rates, with complete conversion occurring

under all conditions at pH 13.5 and 14. Time also played a significant role in conversion rates, from 0% conversion

at pH 13 after 360 minutes of reaction time, to approximately 75% conversion at pH 13 after 15 minutes of reaction

time. The most cost-effective conversions took place at low P

CO2

(10 psi), pH 13 and a reaction time of 15 minutes,

with a conversion rate of around 75%. The results of this study demonstrate that FGD gypsum can serve as a viable

feedstock for CO

2

mineralization, potentially providing an inexpensive method for carbon sequestration.

Biography

Jonathan Riddle received a bachelor’s degree in science at the University of North Alabama. After receiving his degree, he took a hiatus of four years to teach

English in Japan. Afterwards, he decided to continue his geologic career and is currently a master’s student at the University of Alabama. He began studying

environmental issues and was awarded the Outstanding Research Paper from Geosyntec in 2018. He has been working with his professor, Dr. Rona Donahoe,

on carbon mineralization. His is currently investigating more effective ways to use flue gas desulphurization gypsum for CO

2

sequestration. He will be finishing

his master’s degree in December of this year in environmental geochemistry.

Jonathan Riddle et al., J Earth Sci Clim Change 2019, Volume: 10