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Biopolymers and Bioplastics 2016
September 12-14, 2016
Volume 7, Issue 5(Suppl)
J Bioremed Biodeg 2016
ISSN: 2155-6199 JBRBD, an open access journal
conferenceseries
.com
September 12-14, 2016 San Antonio, USA
3
rd
International Conference and Exhibition on
Biopolymers & Bioplastics
Shinji Hirai, J Bioremed Biodeg 2016, 7:5(Suppl)
http://dx.doi.org/10.4172/2155-6199.C1.002Creation of keratin resin and fibroin resin using fibrous animal waste products
Shinji Hirai
Muroran Institute of Technology, Japan
K
eratin resin and fibroin resin have been prepared from silk or hornet silk powder, composed of fibroin protein, and from
wool or chicken feather powder, composed of keratin protein, respectively, by heating at 100–180°C under pressures of 20–
40 MPa. The mechanically ground powders of wool waste or chicken feathers and pulverized waste silk, all of which are waste
materials, can be used as the raw materials. In the case of wool, woven wool fabric also serves as a raw material after removal
of the cuticle layers. For resinification, the powder was simply placed in a jig; in the case of woven fabric, it was stacked into
the jig after punching to the size of the jig and was then heated under pressure using a hot press. The resins derived from silk
or wool powder showed glass transition temperatures close to 200°C and three-point bending strengths and flexural moduli
superior to those of polycarbonate resins. On the other hand, the resin derived from wool powder had a very small expansion
coefficient, with a value comparable to metals such as copper or aluminum. Moreover, the three-point bending strength of the
resin derived from woven wool fabric increased to 116 MPa. Furthermore, upon applying stress to the resin, reversibility to
woven fabric was observed, resulting in excellent impact resistance that is superior to that of ABS resin. Compared to the resins
derived from wool and silk powders, the resin derived from chicken feather powder had a lower glass transition temperature
and a larger thermal expansion coefficient, whereas the three-point bending strength, the elastic modulus, and the Vickers
hardness were found to be lower. However, with the sole exception of the inferior three-point bending strength, the other
features of this resin were comparable with those of polycarbonate.
Biography
Shinji Hirai obtained his PhD in Engineering from Waseda University, Japan in 1988. In 1990, he joined the Department of Materials Science and Engineering,
Muroran Institute of Technology as an Associate Professor. In 1992–1993, he trained under Professor Emeritus L Brewer at the UC Berkeley. In 2003, he acquired
the position of Full Professor and his research interests expanded to include high-performance biomass plastics created using animal fiber waste and effective
utilization of rare earth sulfides. Since 2012, he is concurrently serving as the Director of Research Center for Environmentally Friendly Materials Engineering.
Recently, as part of the ImPACT national project, he is involved in the study of resinification of artificial spider silk.
hirai@mmm.muroran-it.ac.jp