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There exists abundant evidence globally that anthropogenic activities have polluted the environment with heavy metals such
V(V), which eventually find their way into the human food-chain with the subsequent adverse effects. In this study, the
graphite furnace atomic absorption spectrometry (GFAAS) was used in the determination of V(V) and total V in medicinal plants
collected from the farm in the vicinity of the vanadium smelter but unable to sampling the medicinal plants near ferrochrome
smelter. The determination of V(V) in medicinal plants by (GFAAS) was applied based on their leaching with 0.1 M Na2CO3. The
solution was filtered through a PDVF 0.45 mL hydrophilic filter prior analysis by GFAAS. The results suggest that the pyrolysis
temperatures of 1300oC - 1500oC are effective to eliminate the majority of the matrix prior to atomization and any residual
amounts of Na2CO3 had no influence on the release of V during atomization. The concentration of V(VI) in medicinal plants were
in the range between 1.1±0.08 μg g-1-17±1.7 μg g-1 and total V were varied from 18±0.08 μg g-1 and 439±1.6 μg g-1. The procedures
were validated by the analysis of Certified Reference Materials (CRMs): MESS-3, PACS-2, and SRM 2704. The findings from
this study provided the basis for the urgent need to ascertain the levels of V(V) in medicinal plants especially in economically
important plants in farms in the vicinity of mines. This measure is necessary to ensure that the overall aim for better health is not
compromised through possible contamination and toxic effects of these metals.
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