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Climatic changes due to green house gas emissions and substantial increase in the energy costs, demand effective energy
management. In this regard the performance of cooling water systems in various power plants to maintain highest electrical
energy output per tonne of fuel consumed is particularly important. Despite efforts to provide efficient design of heat exchangers
and effective maintenance that involves chlorination and sponge ball cleaning during operation, fouling and corrosion under the
influence of microbes and their biofilms is posing a big threat to this objective. Materials used in cooling water systems like copper
alloys, microalloyed steels, and titanium can undergo biofouling and subsequent degradation under biofilms. Titanium is chosen
as condenser material for the prototype fast breeder reactor at Kalpakkam. To avoid corrosion and biofouling of titanium during
service, extensive investigations were carried out by different methods including nanostructuring of surfaces for making them
antibacterial. The first step was to reduce the microroughness of titanium by repeated pickling which by itself reduced microbial
adhesion. In the second step, anodization of titanium surfaces followed by heat treatment was adopted to control microbial
fouling. This was possible as a consequence of photocatalytic activity under visible light illumination of nanoparticles of anataserutile
combinations produced during anodization. Electroless plating of nanocopper film on titanium surfaces demonstrated
good antibacterial activity. Non-conventional techniques like applied potential and ultrasonication was also attempted to control
biofilm formation on material surfaces to provide antimicrobial activity. Recently superhydrophobic surface modification is
attempted on condenser materials by preparing micro-nano textured surfaces through mechanical and chemical methods, and
providing low surface energy dip coatings, for antibacterial activity. The presentation highlights the above results.
Biography
Rani P. George Leader, Surface Modification Programme, in CSTG, since 1991. She is working on corrosion and biofouling of materials in aquatic
systems. She has 35 papers in reputed journals and has won several awards including NIGIS Award for Excellence in Corrosion Science and
Technology (2010).
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