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Now a days removal of clay waste from waste water of various industries is a major challenge due to their charge and
properties. Flocculation using synthetic polymers has been regarded as a promising process to address this problem.
However, there is a growing concern about the use of synthetic polymers in wastewater. To tackle with this problem, natural
based flocculants (i.e. biodegradable flocculants) should be used for this purpose. In this work, xylan based cationic flocculant
[xylan-2-(methacryloyloxy)ethyl] trimethylammonium chloride (METAC)) was produced and was characterized using gel
permeation chromatography, infrared (FTIR) and elemental analysis. The flocculation potential of produced biopolymer in
removal of clay wastes was studied using two different types of clay suspensions viz., kaolin and bentonite. The biopolymer was
found to be effective in removal of both types of clays via adsorbing on their surface. The removal of clay from suspensions was
due to charge neutralization and polymer bridging mechanisms, which is evident from decrease in relative turbidity of clay
suspensions and change in zeta potential of clay particles. The percentage removal of bentonite and kaolin clay particles from
suspensions was found to be 98 and 80% respectively. The removal of clay particles depends on amount of flocculant adsorbed
on their surface. The floc growth and breakage studies also confirmed the flocculation potential of produced biopolymer. This
work suggest that cationic xylan (biopolymer) can serves as an effective flocculant in removal of clay wastes present in waste
water of various industries.