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Aging wines is a long-used technical step. This praxis was set up for the storage, but later, it has been used because of
its unique effects on wine organoleptic properties. The role of wood during this process is crucial. From the sensorial
point of view, wood is capable of transmitting aroma-responsible volatile compounds. Also, a reduction of astringency and
color changes are produced as a result of the phenolic compounds extraction. Different woods have been used in cooperage
(chestnut, cherry-tree); however oak is the most common for its chemical composition and for both its mechanical and
physical properties. But, the aging carried out by means of barrels entails a time-consuming and expensive practice. On the
one hand, aged wines have to be left in the barrels during a long period before they can be brought to market because of the
slow extraction process of aroma compounds. On the other hand, it implies some problems, such as their sanitization and
handling. The volatile composition of Quercus pyrenaica from NW Spain were analyzed on a wide sample set of more than 100.
The relationship between some silvicultural and site parameters and volatile composition was studied. Altitude appeared to
be the most significant parameter. However, other factors such as annual precipitation and number of trees per hectare whose
effects on the volatile compounds were not significant. The influence of geographical location seemed to have a more specific
impact. The content of extractable compounds permitted a separation of samples according to their origin.