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September 02-03, 2019 | Berlin, Germany

6

th

World Conference on Climate Change

Volume 10

Journal of Earth Science & Climatic Change

ISSN: 2157-7617

Climate Change 2019

September 02-03, 2019

Comprehensive review of chemical and mechanical degradation of well cement in Co

2

environment for

Ccs operations

Priyesh Jani

and

Abdulmohsin Imqam

Missouri University of Science and Technology, USA

Statement of the Problem:

Carbon capture and storage operations reduce emission of carbon dioxide into the

atmosphere which has a large impact on the environment. Long-term storage of carbon dioxide in a reservoir

depends on the degradation of Portland cement used to cast these wells due to carbon dioxide. The objective of this

research is to provide a comprehensive review of past investigations to help understand the cement’s degradation, the

provided solutions to this problem and discuss a potential alternative.

Methodology:

Tables were made with information about the types of cement, the curing conditions and the

exposure conditions (experimental conditions) used in different studies and their conclusions. Tables comprised

of experimental studies conducted on neat Portland cement and cement mix (Portland cement + additives) were

included. Field studies were also discussed. Possible migration paths of CO

2

and exposure conditions that are

likely to happen inside the reservoir were discussed. Quantitative data was extracted from these investigations to

understand the structural changes after the exposure. Histograms were made from the data acquired to determine

the most used type of cement, exposure condition and additive. The data were constructed to explain different curing

and exposure conditions.

Findings:

Data analysis shows that wide ranges of curing and exposure conditions made the comparison of structural

changes impossible between the studies. However, the increase or decrease in porosity, strength, permeability and

density of cement cores after CO

2

exposure, and alteration depths were compared. Mostly, researchers used class

H and class G well cement with CO

2

saturated brine/water at static conditions. Flyash is found to be best known

pozzolan and can be reliably mixed with cement to provide long term integrity in CO

2

storage operations. However,

studies suggest that higher amounts of this additive have a negative impact on the cement mix for this environment.

Flyash-based geopolymer cement was suggested to be used in CO

2

storage operations due to its environmentally

friendly nature and higher durability in CO

2

environment than Portland cement.

Novel Information:

The research provided a critical review about the past investigations, which became helpful in

understanding the degradation process of Portland cement in a CO

2

environment and the behavior of additives. A

new flyash-based geopolymer cement was proposed and discussed.

J Earth Sci Clim Change 2019, Volume: 10