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.com
Volume 8, Issue 2 (Suppl)
Chem Sci J 2017
ISSN: 2150-3494 CSJ, an open access journal
Euro Chemistry 2017
May 11-13, 2017
May 11-13, 2017 Barcelona, Spain
4
th
European Chemistry Congress
Theoretical IR, UV,
1
H and
13
C-NMR spectra of certain Schiff bases derived substituted-2-aminophenol
and hydroxyl benzaldehyde
Dila Ercengiz
1
, Halil Berber
2
and
Ulku Dilek Uysal
2
1,2
Anadolu University,Turkey
S
chiff bases are compounds formed by the condensation of an active carbonyl group with primary amine or N-substituted imine
containing an imino group (R-C=N-). They have been used as ligands, liquid crystals, heterogeneous catalysts, high-performance
organic light emitting diodes (OLED), and to design molecular ferromagnet, in catalysis and biological applications [1]. In this study,
five Schiff bases (Figure 1) have been synthesized and characterized with
1
H and
13
C-NMR. These Schiff bases’ Gibbs Free Energies,
Dipole moments, HOMO-LUMO values, theoretical IR, UV,
1
H and
13
C-NMR spectra have been researched by DFT method
with Gaussian09 program (B3LYP/6-311++G(d,p)) [2] and compared than those with experimental values. Structure- reactivity
relationship for these molecules was also searched.
Figure 1.
The studied Schiff bases.
Biography
Dila Ercengiz has completed her Bachelor’s degree in 2015 from Anadolu University. She is student of Anadolu University at Graduate School of Sciences.
dercengiz@anadolu.edu.trDila Ercengiz et al., Chem Sci J 2017, 8:2(Suppl)
http://dx.doi.org/10.4172/2150-3494-C1-009OH
O
N
HO
R
1
R
2
O
O
OH
R
2
NH
2
OH
R
1
=H; R
2
=Cl, CH
3,
NO
2
R
2
H; R
1
=Cl, CH
3
R
1